You can create a new module and create an adminhtml folder in the etc folder. Here, create a system.xml and add the following code:
<config xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:noNamespaceSchemaLocation="urn:magento:module:Magento_Config:etc/system_file.xsd">
<system>
<section id="trans_email" translate="label" type="text" sortOrder="90" showInDefault="1" showInWebsite="1" showInStore="1">
<tab>general</tab>
<group id="ident_custom3" translate="label" type="text" sortOrder="6" showInDefault="1" showInWebsite="1" showInStore="1">
<label>Custom Email 3</label>
<field id="email" translate="label" type="text" sortOrder="2" showInDefault="1" showInWebsite="1" showInStore="1" canRestore="1">
<label>Sender Email</label>
<validate>validate-email</validate>
<backend_model>Magento\Config\Model\Config\Backend\Email\Address</backend_model>
</field>
<field id="name" translate="label" type="text" sortOrder="1" showInDefault="1" showInWebsite="1" showInStore="1" canRestore="1">
<label>Sender Name</label>
<backend_model>Magento\Config\Model\Config\Backend\Email\Sender</backend_model>
<validate>validate-emailSender</validate>
</field>
</group>
</section>
</system>
</config>
This will add a Custom Email 3 section at Stores ->Configurations ->General ->Store Email Addresses.
**粗体** _斜体_ [链接](http://example.com) `代码` - 列表 > 引用
。你还可以使用@
来通知其他用户。